{"id":6383,"date":"2024-10-03T19:54:31","date_gmt":"2024-10-03T19:54:31","guid":{"rendered":"https:\/\/www.tun.com\/home\/?p=6383"},"modified":"2024-10-16T20:52:51","modified_gmt":"2024-10-16T20:52:51","slug":"researchers-break-new-ground-with-high-energy-density-cubic-gauche-nitrogen-synthesis-at-atmospheric-pressure","status":"publish","type":"post","link":"https:\/\/www.tun.com\/home\/researchers-break-new-ground-with-high-energy-density-cubic-gauche-nitrogen-synthesis-at-atmospheric-pressure\/","title":{"rendered":"Researchers Break New Ground With High-Energy-Density Cubic Gauche Nitrogen Synthesis at Atmospheric Pressure"},"content":{"rendered":"\n<div class=\"wp-block-group\"><div class=\"wp-block-group__inner-container is-layout-constrained wp-block-group-is-layout-constrained\">\n<div class=\"wp-block-uagb-blockquote uagb-block-e7eb3fc3 uagb-blockquote__skin-border uagb-blockquote__stack-img-none\"><blockquote class=\"uagb-blockquote\"><div class=\"uagb-blockquote__content\">A new study led by Wang Xianlong at the Hefei Institutes of Physical Science has resulted in the atmospheric pressure synthesis of cubic gauche nitrogen, a high-energy-density material with promising applications.<\/div><footer><div class=\"uagb-blockquote__author-wrap uagb-blockquote__author-at-left\"><\/div><\/footer><\/blockquote><\/div>\n\n\n\n<div class=\"wp-block-group is-content-justification-space-between is-nowrap is-layout-flex wp-container-core-group-is-layout-b0ffac9c wp-block-group-is-layout-flex\"><div style=\"font-size:16px\" class=\"has-text-align-left wp-block-post-author\"><div class=\"wp-block-post-author__content\"><p class=\"wp-block-post-author__name\">The University Network<\/p><\/div><\/div>\n\n\n<div class=\"wp-block-uagb-social-share uagb-social-share__outer-wrap uagb-social-share__layout-horizontal uagb-block-ee584a31\">\n<div class=\"wp-block-uagb-social-share-child uagb-ss-repeater uagb-ss__wrapper uagb-block-ec619ce7\"><span class=\"uagb-ss__link\" data-href=\"https:\/\/www.facebook.com\/sharer.php?u=\" tabindex=\"0\" role=\"button\" aria-label=\"facebook\"><span class=\"uagb-ss__source-wrap\"><span class=\"uagb-ss__source-icon\"><svg xmlns=\"https:\/\/www.w3.org\/2000\/svg\" viewBox=\"0 0 512 512\"><path d=\"M504 256C504 119 393 8 256 8S8 119 8 256c0 123.8 90.69 226.4 209.3 245V327.7h-63V256h63v-54.64c0-62.15 37-96.48 93.67-96.48 27.14 0 55.52 4.84 55.52 4.84v61h-31.28c-30.8 0-40.41 19.12-40.41 38.73V256h68.78l-11 71.69h-57.78V501C413.3 482.4 504 379.8 504 256z\"><\/path><\/svg><\/span><\/span><\/span><\/div>\n\n\n\n<div class=\"wp-block-uagb-social-share-child uagb-ss-repeater uagb-ss__wrapper uagb-block-32d99934\"><span class=\"uagb-ss__link\" data-href=\"https:\/\/twitter.com\/share?url=\" tabindex=\"0\" role=\"button\" aria-label=\"twitter\"><span class=\"uagb-ss__source-wrap\"><span class=\"uagb-ss__source-icon\"><svg xmlns=\"https:\/\/www.w3.org\/2000\/svg\" viewBox=\"0 0 512 512\"><path d=\"M389.2 48h70.6L305.6 224.2 487 464H345L233.7 318.6 106.5 464H35.8L200.7 275.5 26.8 48H172.4L272.9 180.9 389.2 48zM364.4 421.8h39.1L151.1 88h-42L364.4 421.8z\"><\/path><\/svg><\/span><\/span><\/span><\/div>\n\n\n\n<div class=\"wp-block-uagb-social-share-child uagb-ss-repeater uagb-ss__wrapper uagb-block-1d136f14\"><span class=\"uagb-ss__link\" data-href=\"https:\/\/www.linkedin.com\/shareArticle?url=\" tabindex=\"0\" role=\"button\" aria-label=\"linkedin\"><span class=\"uagb-ss__source-wrap\"><span class=\"uagb-ss__source-icon\"><svg xmlns=\"https:\/\/www.w3.org\/2000\/svg\" viewBox=\"0 0 448 512\"><path d=\"M416 32H31.9C14.3 32 0 46.5 0 64.3v383.4C0 465.5 14.3 480 31.9 480H416c17.6 0 32-14.5 32-32.3V64.3c0-17.8-14.4-32.3-32-32.3zM135.4 416H69V202.2h66.5V416zm-33.2-243c-21.3 0-38.5-17.3-38.5-38.5S80.9 96 102.2 96c21.2 0 38.5 17.3 38.5 38.5 0 21.3-17.2 38.5-38.5 38.5zm282.1 243h-66.4V312c0-24.8-.5-56.7-34.5-56.7-34.6 0-39.9 27-39.9 54.9V416h-66.4V202.2h63.7v29.2h.9c8.9-16.8 30.6-34.5 62.9-34.5 67.2 0 79.7 44.3 79.7 101.9V416z\"><\/path><\/svg><\/span><\/span><\/span><\/div>\n<\/div>\n<\/div>\n<\/div><\/div>\n\n\n\n<p class=\"wp-block-paragraph\"><\/p>\n\n\n\n<p class=\"wp-block-paragraph\">In a significant scientific breakthrough, researchers from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences have successfully <a href=\"https:\/\/english.cas.cn\/newsroom\/research_news\/phys\/202409\/t20240925_690606.shtml\">synthesized<\/a> cubic gauche nitrogen (cg-N) at atmospheric pressure. The research, led by Wang Xianlong, utilized potassium azide (KN3) and the plasma-enhanced chemical vapor deposition (PECVD) technique to achieve this milestone. The results of the study were recently <a href=\"https:\/\/www.science.org\/doi\/10.1126\/sciadv.adq5299\" title=\"\">published<\/a> in the journal Science Advances.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Cubic gauche nitrogen is composed entirely of nitrogen atoms interconnected through N-N single bonds, mimicking the structure of diamond. This material has drawn considerable attention due to its high-energy-density and the fact that it decomposes into harmless nitrogen gas. Achieving a safe and efficient synthesis method for cg-N at atmospheric pressure has been an ongoing challenge in the field.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">Since 2020, Wang&#8217;s team has employed first-principles calculations to simulate the stability of the cg-N surface under various conditions, including different pressures and temperatures. Their findings indicated that surface instability caused cg-N to decompose at low pressures. By saturating the surface suspension bonds and managing charge transfer, the researchers have now managed to stabilize cg-N up to 750 K at atmospheric pressure.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">In their recent study, the team opted to use potassium azide, known for its lower toxicity and explosive risk, as the precursor. The strong electron transfer capability of potassium played a crucial role in the successful synthesis of cg-N using PECVD. This method did not require the previously essential carbon nanotube-limiting effect. Further validation came from thermogravimetric-differential scanning calorimetry (TG-DSC) measurements, confirming that the synthesized cg-N maintains thermal stability up to 760 K, though it undergoes rapid and intense decomposition at higher temperatures.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">This advancement represents not only an efficient and convenient method for synthesizing cg-N at atmospheric pressure but also opens new avenues for developing high-energy-density materials. The potential applications of cg-N are vast, potentially transforming energy storage and other sectors reliant on high-energy materials.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\">The significance of this research is profound. High-energy-density materials like cg-N have the potential to revolutionize various industries, including aerospace, defense and energy storage, by providing more efficient and safer alternatives. As cg-N decomposes only into nitrogen gas, it offers an environmentally friendly solution, reducing potential hazardous byproducts.<\/p>\n\n\n\n<p class=\"wp-block-paragraph\"><\/p>\n","protected":false},"excerpt":{"rendered":"<p>In a significant scientific breakthrough, researchers from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences have successfully synthesized cubic gauche nitrogen (cg-N) at atmospheric pressure. The research, led by Wang Xianlong, utilized potassium azide (KN3) and the plasma-enhanced chemical vapor deposition (PECVD) technique to achieve this milestone. The results of the [&hellip;]<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"single-no-separators","format":"standard","meta":{"_acf_changed":false,"_uag_custom_page_level_css":"","_monsterinsights_skip_tracking":false,"footnotes":""},"categories":[10],"tags":[],"class_list":["post-6383","post","type-post","status-publish","format-standard","hentry","category-sustainability"],"acf":[],"aioseo_notices":[],"aioseo_head":"\n\t\t<!-- All in One SEO 4.9.8 - aioseo.com -->\n\t<meta name=\"description\" content=\"Scientists from Hefei Institutes of Physical Science have successfully synthesized cubic gauche nitrogen at atmospheric pressure, paving the way for new high-energy-density materials.\" \/>\n\t<meta name=\"robots\" content=\"max-image-preview:large\" \/>\n\t<meta name=\"author\" content=\"The University Network\"\/>\n\t<link rel=\"canonical\" href=\"https:\/\/www.tun.com\/home\/researchers-break-new-ground-with-high-energy-density-cubic-gauche-nitrogen-synthesis-at-atmospheric-pressure\/\" \/>\n\t<meta name=\"generator\" content=\"All in One SEO (AIOSEO) 4.9.8\" \/>\n\t\t<meta property=\"og:locale\" content=\"en_US\" \/>\n\t\t<meta property=\"og:site_name\" content=\"TUN - 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The research, led by Wang Xianlong, utilized potassium azide (KN3) and the plasma-enhanced chemical vapor deposition (PECVD) technique to achieve this milestone. The results of the&hellip;","_links":{"self":[{"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/posts\/6383","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/comments?post=6383"}],"version-history":[{"count":5,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/posts\/6383\/revisions"}],"predecessor-version":[{"id":6616,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/posts\/6383\/revisions\/6616"}],"wp:attachment":[{"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/media?parent=6383"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/categories?post=6383"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.tun.com\/home\/wp-json\/wp\/v2\/tags?post=6383"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}