{"id":24150,"date":"2018-05-22T12:32:31","date_gmt":"2018-05-22T16:32:31","guid":{"rendered":"https:\/\/www.tun.com\/blog\/?p=24150"},"modified":"2022-03-16T11:55:56","modified_gmt":"2022-03-16T15:55:56","slug":"new-sustainable-method-of-ammonia-production","status":"publish","type":"post","link":"https:\/\/www.tun.com\/blog\/new-sustainable-method-of-ammonia-production\/","title":{"rendered":"The Significance of New Sustainable Method of Ammonia Production"},"content":{"rendered":"<p><span style=\"font-weight: 400;\">Researchers from the University of Central Florida (UCF) and Virginia Tech have developed a <\/span><a href=\"https:\/\/today.ucf.edu\/green-approach-making-ammonia-help-feed-world\/\"><span style=\"font-weight: 400;\">sustainable method of producing ammonia<\/span><\/a><span style=\"font-weight: 400;\">, a compound of nitrogen and hydrogen, which is vital for life on earth, including the production of food to feed the increasing world population. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">The advancement is an important step toward sustainability for an industry long dependent on fossil fuels, and could lead to a greener way to feed the world.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">The paper is published in the journal <\/span><a href=\"https:\/\/www.nature.com\/articles\/s41467-018-04213-9\"><span style=\"font-weight: 400;\">Nature Communications<\/span><\/a><span style=\"font-weight: 400;\">.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">Ammonia plays an important role in the manufacture of a wide variety of products, from textiles to explosives. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">Because it holds so much value in a wide variety of industries, ammonia is one of the most highly produced inorganic chemicals in the world, with the U.S. being one of the world\u2019s leading producers and consumers. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">About <\/span><a href=\"https:\/\/minerals.usgs.gov\/minerals\/pubs\/commodity\/nitrogen\/mcs-2017-nitro.pdf\"><span style=\"font-weight: 400;\">88 percent<\/span><\/a><span style=\"font-weight: 400;\"> of ammonia in the U.S. is used for fertilisers. <\/span><\/p>\n<h2><b>Problems with existing methods<\/b><\/h2>\n<p><span style=\"font-weight: 400;\">For all that ammonia provides as a fertilizer, its production comes with major environmental costs. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">The <\/span><a href=\"https:\/\/www.princeton.edu\/~hos\/mike\/texts\/readmach\/zmaczynski.htm\"><span style=\"font-weight: 400;\">Haber-Bosch process<\/span><\/a><span style=\"font-weight: 400;\">, which has been the most common method of ammonia production since World War I, requires high temperatures and tremendous pressure. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">Nitrogen and hydrogen molecules must be heated to temperatures between <\/span><span style=\"font-weight: 400;\">662\u00b0 to 1022\u00b0 F <\/span><span style=\"font-weight: 400;\">under between 2,200 and 5,100 pounds per square inch of pressure. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">As a result, the process consumes 1-2 percent of the global annual energy supply, said <\/span><a href=\"https:\/\/sciences.ucf.edu\/physics\/people\/feng-xiaofeng\/\"><span style=\"font-weight: 400;\">Xiaofeng Feng<\/span><\/a><span style=\"font-weight: 400;\">, an assistant professor of physics at UCF who led the research team. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">So while the invention of this process helped spur the rise of large-scale industrial agriculture to feed the ever-growing world population, it is responsible for prolific greenhouse gas emissions &#8212; about <\/span><a href=\"http:\/\/www.newsweek.com\/haber-bosch-fertilizer-natural-gas-fossil-fuels-460895\"><span style=\"font-weight: 400;\">3 percent of the world\u2019s carbon emissions<\/span><\/a><span style=\"font-weight: 400;\"> &#8212; and groundwater contamination, both of which are detrimental to local ecosystems and the global environment.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">The heavy environmental costs have inspired many recent efforts to make ammonia production more sustainable. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">One approach that scientists have been exploring is finding ways to produce the chemical under milder conditions and using electrical energy. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">\u201cAn electrochemical approach can enable <\/span><i><span style=\"font-weight: 400;\">sustainable<\/span><\/i><span style=\"font-weight: 400;\"> ammonia synthesis using electricity from renewable energy sources such as solar and wind,\u201d said Feng.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">Unfortunately, electrochemical methods have proven to this point to be too inefficient to be used in large-scale ammonia production. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">They have typically used a conventional mechanism, called a \u201cproton-coupled electron transfer process,\u201d in which active electrons passed through an electrode are used to drive the reaction, with water serving as the hydrogen source. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">Through this method, ammonia is produced, albeit inefficiently and at a low reaction rate.<\/span><\/p>\n<h2><b>Feng\u2019s improved method<\/b><\/h2>\n<p><span style=\"font-weight: 400;\">Feng\u2019s team, however, has found a way to develop more energy-efficient electrochemical processes. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">The method uses palladium hydride as a catalyst, which enables the electrons to be used much more efficiently. <\/span><\/p>\n<p><span style=\"font-weight: 400;\">Palladium, which is highly active for hydrogen evolution reaction, a reaction that competes with the ammonia synthesis reaction, had previously received little attention as a catalyst for electrochemical ammonia production, Feng explained.<\/span><\/p>\n<p><span style=\"font-weight: 400;\">\u201cOur research discovered that palladium catalyst can enable a high activity and selectivity with a minimal overpotential (or electrical energy), due to a unique hydride transfer mechanism enabled by palladium hydride,\u201d he said. \u201cThis new mechanism may not only provide a new route for sustainable ammonia synthesis, but also inspire peer researchers to use the principle to address other reactions for renewable energy conversion.\u201d<\/span><\/p>\n<h2><b>What\u2019s next?<\/b><\/h2>\n<p><span style=\"font-weight: 400;\">Moving forward, the researchers intend to continue to develop and optimize their method of ammonia synthesis.<\/span><span style=\"font-weight: 400;\">\u201cOur next step is to further understand and improve the catalytic process using advanced techniques such as synchrotron-based X-ray spectroscopy and gas-diffusion electrode,\u201d said Feng. \u201cWe will also develop more efficient catalysts with low palladium loading or non-precious metals for ammonia synthesis.\u201d<\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Researchers from the University of Central Florida (UCF) and Virginia Tech have developed a sustainable method of producing ammonia, a compound of nitrogen and hydrogen, which is vital for life on earth, including the production of food to feed the increasing world population. The advancement is an important step toward sustainability for an industry long [&hellip;]<\/p>\n","protected":false},"author":61,"featured_media":45262,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"om_disable_all_campaigns":false,"_uag_custom_page_level_css":"","_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[233,638,230,640,229,252,572,243],"tags":[],"class_list":["post-24150","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-sustainable","category-food-security","category-news","category-sustainable-agriculture","category-lead-stories","category-university-of-central-florida","category-virginia-polytechnic-institute-and-state-university","category-health"],"aioseo_notices":[],"uagb_featured_image_src":{"full":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg",830,533,false],"thumbnail":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production-224x144.jpg",224,144,true],"medium":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production-300x193.jpg",300,193,true],"medium_large":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg",830,533,false],"large":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg",830,533,false],"1536x1536":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg",830,533,false],"2048x2048":["https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg",830,533,false]},"uagb_author_info":{"display_name":"Sam Benezra","author_link":"https:\/\/www.tun.com\/blog\/author\/sam-benezra\/"},"uagb_comment_info":0,"uagb_excerpt":"Researchers from the University of Central Florida (UCF) and Virginia Tech have developed a sustainable method of producing ammonia, a compound of nitrogen and hydrogen, which is vital for life on earth, including the production of food to feed the increasing world population. The advancement is an important step toward sustainability for an industry long&hellip;","featured_media_src_url":"https:\/\/www.tun.com\/blog\/wp-content\/uploads\/2018\/05\/New-Sustainable-Method-Of-Ammonia-Production.jpg","_links":{"self":[{"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/posts\/24150","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/users\/61"}],"replies":[{"embeddable":true,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/comments?post=24150"}],"version-history":[{"count":0,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/posts\/24150\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/media\/45262"}],"wp:attachment":[{"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/media?parent=24150"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/categories?post=24150"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.tun.com\/blog\/wp-json\/wp\/v2\/tags?post=24150"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}